| 2021-12-21 | VillarrealvAlavesLa Liga · Spain | 5–2 | La Liga · Spain |
| 2021-12-18 | SociedadvVillarrealLa Liga · Spain | 1–3 | La Liga · Spain |
| 2021-12-12 | VillarrealvVallecanoLa Liga · Spain | 2–0 | La Liga · Spain |
| 2021-12-04 | SevillavVillarrealLa Liga · Spain | 1–0 | La Liga · Spain |
| 2021-11-27 | VillarrealvBarcelonaLa Liga · Spain | 1–3 | La Liga · Spain |
| 2021-11-20 | CeltavVillarrealLa Liga · Spain | 1–1 | La Liga · Spain |
| 2021-11-07 | VillarrealvGetafeLa Liga · Spain | 1–0 | La Liga · Spain |
| 2021-10-30 | ValenciavVillarrealLa Liga · Spain | 2–0 | La Liga · Spain |
| 2021-10-26 | VillarrealvCadizLa Liga · Spain | 3–3 | La Liga · Spain |
| 2021-10-23 | Ath BilbaovVillarrealLa Liga · Spain | 2–1 | La Liga · Spain |
| 2021-10-17 | VillarrealvOsasunaLa Liga · Spain | 1–2 | La Liga · Spain |
| 2021-10-03 | VillarrealvBetisLa Liga · Spain | 2–0 | La Liga · Spain |
| 2021-09-25 | Real MadridvVillarrealLa Liga · Spain | 0–0 | La Liga · Spain |
| 2021-09-22 | VillarrealvElcheLa Liga · Spain | 4–1 | La Liga · Spain |
| 2021-09-19 | MallorcavVillarrealLa Liga · Spain | 0–0 | La Liga · Spain |
| 2021-08-29 | Ath MadridvVillarrealLa Liga · Spain | 2–2 | La Liga · Spain |
| 2021-08-21 | EspanolvVillarrealLa Liga · Spain | 0–0 | La Liga · Spain |
| 2021-08-16 | VillarrealvGranadaLa Liga · Spain | 0–0 | La Liga · Spain |
| 2021-05-22 | Real MadridvVillarrealLa Liga · Spain | 2–1 | La Liga · Spain |
| 2021-05-16 | VillarrealvSevillaLa Liga · Spain | 4–0 | La Liga · Spain |
| 2021-05-13 | ValladolidvVillarrealLa Liga · Spain | 0–2 | La Liga · Spain |
| 2021-05-09 | VillarrealvCeltaLa Liga · Spain | 2–4 | La Liga · Spain |
| 2021-05-02 | VillarrealvGetafeLa Liga · Spain | 1–0 | La Liga · Spain |
| 2021-04-25 | VillarrealvBarcelonaLa Liga · Spain | 1–2 | La Liga · Spain |
| 2021-04-21 | AlavesvVillarrealLa Liga · Spain | 2–1 | La Liga · Spain |
| 2021-04-18 | LevantevVillarrealLa Liga · Spain | 1–5 | La Liga · Spain |
| 2021-04-11 | VillarrealvOsasunaLa Liga · Spain | 1–2 | La Liga · Spain |
| 2021-04-03 | GranadavVillarrealLa Liga · Spain | 0–3 | La Liga · Spain |
| 2021-03-21 | VillarrealvCadizLa Liga · Spain | 2–1 | La Liga · Spain |
| 2021-03-14 | EibarvVillarrealLa Liga · Spain | 1–3 | La Liga · Spain |
| 2021-03-05 | ValenciavVillarrealLa Liga · Spain | 2–1 | La Liga · Spain |
| 2021-02-28 | VillarrealvAth MadridLa Liga · Spain | 0–2 | La Liga · Spain |
| 2021-02-21 | Ath BilbaovVillarrealLa Liga · Spain | 1–1 | La Liga · Spain |
| 2021-02-14 | VillarrealvBetisLa Liga · Spain | 1–2 | La Liga · Spain |
| 2021-02-06 | ElchevVillarrealLa Liga · Spain | 2–2 | La Liga · Spain |
| 2021-01-30 | VillarrealvSociedadLa Liga · Spain | 1–1 | La Liga · Spain |
| 2021-01-23 | HuescavVillarrealLa Liga · Spain | 0–0 | La Liga · Spain |
| 2021-01-20 | VillarrealvGranadaLa Liga · Spain | 2–2 | La Liga · Spain |
| 2021-01-08 | CeltavVillarrealLa Liga · Spain | 0–4 | La Liga · Spain |
| 2021-01-02 | VillarrealvLevanteLa Liga · Spain | 2–1 | La Liga · Spain |