| 2000-12-20 | SantandervValladolidLaLiga · Spain | 2–2 | LaLiga · Spain |
| 2000-12-17 | ValladolidvAth BilbaoLaLiga · Spain | 0–0 | LaLiga · Spain |
| 2000-12-10 | MalagavValladolidLaLiga · Spain | 3–1 | LaLiga · Spain |
| 2000-12-02 | ValladolidvValenciaLaLiga · Spain | 0–0 | LaLiga · Spain |
| 2000-11-26 | ValladolidvSociedadLaLiga · Spain | 2–1 | LaLiga · Spain |
| 2000-11-19 | OviedovValladolidLaLiga · Spain | 4–1 | LaLiga · Spain |
| 2000-11-12 | ValladolidvAlavesLaLiga · Spain | 2–1 | LaLiga · Spain |
| 2000-11-05 | VallecanovValladolidLaLiga · Spain | 2–1 | LaLiga · Spain |
| 2000-11-01 | ValladolidvEspanolLaLiga · Spain | 1–1 | LaLiga · Spain |
| 2000-10-29 | CeltavValladolidLaLiga · Spain | 2–1 | LaLiga · Spain |
| 2000-10-22 | ValladolidvOsasunaLaLiga · Spain | 1–1 | LaLiga · Spain |
| 2000-10-15 | ZaragozavValladolidLaLiga · Spain | 0–0 | LaLiga · Spain |
| 2000-10-01 | ValladolidvVillarrealLaLiga · Spain | 0–0 | LaLiga · Spain |
| 2000-09-23 | Las PalmasvValladolidLaLiga · Spain | 1–1 | LaLiga · Spain |
| 2000-09-16 | ValladolidvNumanciaLaLiga · Spain | 2–0 | LaLiga · Spain |
| 2000-09-10 | MallorcavValladolidLaLiga · Spain | 1–1 | LaLiga · Spain |
| 2000-05-19 | Real MadridvValladolidLaLiga · Spain | 0–1 | LaLiga · Spain |
| 2000-05-14 | ValladolidvMallorcaLaLiga · Spain | 2–1 | LaLiga · Spain |
| 2000-05-07 | ValladolidvBetisLaLiga · Spain | 0–3 | LaLiga · Spain |
| 2000-04-30 | AlavesvValladolidLaLiga · Spain | 1–0 | LaLiga · Spain |
| 2000-04-22 | ValladolidvEspanolLaLiga · Spain | 1–0 | LaLiga · Spain |
| 2000-04-16 | SantandervValladolidLaLiga · Spain | 1–1 | LaLiga · Spain |
| 2000-04-09 | ValladolidvZaragozaLaLiga · Spain | 1–1 | LaLiga · Spain |
| 2000-04-02 | CeltavValladolidLaLiga · Spain | 1–1 | LaLiga · Spain |
| 2000-03-25 | ValladolidvSociedadLaLiga · Spain | 2–1 | LaLiga · Spain |
| 2000-03-19 | VallecanovValladolidLaLiga · Spain | 4–1 | LaLiga · Spain |
| 2000-03-12 | ValladolidvAth MadridLaLiga · Spain | 1–0 | LaLiga · Spain |
| 2000-03-05 | SevillavValladolidLaLiga · Spain | 0–1 | LaLiga · Spain |
| 2000-02-27 | ValladolidvOviedoLaLiga · Spain | 2–1 | LaLiga · Spain |
| 2000-02-20 | BarcelonavValladolidLaLiga · Spain | 4–0 | LaLiga · Spain |
| 2000-02-15 | ValladolidvReal MadridLaLiga · Spain | 0–1 | LaLiga · Spain |
| 2000-02-12 | ValladolidvValenciaLaLiga · Spain | 0–0 | LaLiga · Spain |
| 2000-02-06 | MalagavValladolidLaLiga · Spain | 0–0 | LaLiga · Spain |
| 2000-01-30 | ValladolidvLa CorunaLaLiga · Spain | 4–1 | LaLiga · Spain |
| 2000-01-23 | Ath BilbaovValladolidLaLiga · Spain | 1–0 | LaLiga · Spain |
| 2000-01-16 | ValladolidvNumanciaLaLiga · Spain | 2–0 | LaLiga · Spain |
| 2000-01-05 | MallorcavValladolidLaLiga · Spain | 0–0 | LaLiga · Spain |