| 1994-12-22 | ValladolidvReal MadridLa Liga · Spain | 0–5 | La Liga · Spain |
| 1994-12-11 | BetisvValladolidLa Liga · Spain | 1–2 | La Liga · Spain |
| 1994-12-04 | ValladolidvCeltaLa Liga · Spain | 1–1 | La Liga · Spain |
| 1994-11-27 | La CorunavValladolidLa Liga · Spain | 4–0 | La Liga · Spain |
| 1994-11-19 | ValladolidvBarcelonaLa Liga · Spain | 1–3 | La Liga · Spain |
| 1994-11-06 | ValladolidvSevillaLa Liga · Spain | 0–4 | La Liga · Spain |
| 1994-10-30 | OviedovValladolidLa Liga · Spain | 1–0 | La Liga · Spain |
| 1994-10-23 | ValladolidvSociedadLa Liga · Spain | 1–1 | La Liga · Spain |
| 1994-10-16 | TenerifevValladolidLa Liga · Spain | 0–0 | La Liga · Spain |
| 1994-10-09 | ValladolidvValenciaLa Liga · Spain | 2–0 | La Liga · Spain |
| 1994-10-02 | Ath MadridvValladolidLa Liga · Spain | 6–0 | La Liga · Spain |
| 1994-09-24 | ValladolidvZaragozaLa Liga · Spain | 2–0 | La Liga · Spain |
| 1994-09-18 | CompostelavValladolidLa Liga · Spain | 1–0 | La Liga · Spain |
| 1994-09-11 | ValladolidvEspanolLa Liga · Spain | 0–4 | La Liga · Spain |
| 1994-09-04 | SantandervValladolidLa Liga · Spain | 0–0 | La Liga · Spain |
| 1994-05-15 | ValladolidvCeltaLa Liga · Spain | 0–0 | La Liga · Spain |
| 1994-05-08 | ValenciavValladolidLa Liga · Spain | 5–1 | La Liga · Spain |
| 1994-05-01 | ValladolidvLogronesLa Liga · Spain | 2–0 | La Liga · Spain |
| 1994-04-24 | VallecanovValladolidLa Liga · Spain | 0–1 | La Liga · Spain |
| 1994-04-17 | ValladolidvLeridaLa Liga · Spain | 0–2 | La Liga · Spain |
| 1994-04-10 | TenerifevValladolidLa Liga · Spain | 0–2 | La Liga · Spain |
| 1994-04-06 | ValladolidvSantanderLa Liga · Spain | 0–3 | La Liga · Spain |
| 1994-04-03 | Ath MadridvValladolidLa Liga · Spain | 2–0 | La Liga · Spain |
| 1994-03-27 | ValladolidvOviedoLa Liga · Spain | 0–0 | La Liga · Spain |
| 1994-03-20 | La CorunavValladolidLa Liga · Spain | 0–0 | La Liga · Spain |
| 1994-03-13 | ValladolidvAth BilbaoLa Liga · Spain | 1–1 | La Liga · Spain |
| 1994-03-06 | ValladolidvOsasunaLa Liga · Spain | 2–1 | La Liga · Spain |
| 1994-02-27 | ZaragozavValladolidLa Liga · Spain | 2–0 | La Liga · Spain |
| 1994-02-23 | ValladolidvBarcelonaLa Liga · Spain | 1–3 | La Liga · Spain |
| 1994-02-20 | AlbacetevValladolidLa Liga · Spain | 1–1 | La Liga · Spain |
| 1994-02-13 | ValladolidvSociedadLa Liga · Spain | 0–0 | La Liga · Spain |
| 1994-02-06 | SevillavValladolidLa Liga · Spain | 3–3 | La Liga · Spain |
| 1994-01-30 | ValladolidvReal MadridLa Liga · Spain | 0–0 | La Liga · Spain |
| 1994-01-23 | Sp GijonvValladolidLa Liga · Spain | 2–0 | La Liga · Spain |
| 1994-01-16 | CeltavValladolidLa Liga · Spain | 1–2 | La Liga · Spain |
| 1994-01-09 | ValladolidvValenciaLa Liga · Spain | 1–1 | La Liga · Spain |
| 1994-01-02 | LogronesvValladolidLa Liga · Spain | 0–0 | La Liga · Spain |