| 2024-12-21 | Werder BremenvUnion BerlinBundesliga · Germany | 4–1 | Bundesliga · Germany |
| 2024-12-14 | Union BerlinvBochumBundesliga · Germany | 0–2 | Bundesliga · Germany |
| 2024-12-06 | StuttgartvUnion BerlinBundesliga · Germany | 3–2 | Bundesliga · Germany |
| 2024-11-30 | Union BerlinvLeverkusenBundesliga · Germany | 1–2 | Bundesliga · Germany |
| 2024-11-23 | WolfsburgvUnion BerlinBundesliga · Germany | 1–0 | Bundesliga · Germany |
| 2024-11-08 | Union BerlinvFreiburgBundesliga · Germany | 0–0 | Bundesliga · Germany |
| 2024-11-02 | Bayern MunichvUnion BerlinBundesliga · Germany | 3–0 | Bundesliga · Germany |
| 2024-10-27 | Union BerlinvEin FrankfurtBundesliga · Germany | 1–1 | Bundesliga · Germany |
| 2024-10-20 | Holstein KielvUnion BerlinBundesliga · Germany | 0–2 | Bundesliga · Germany |
| 2024-10-05 | Union BerlinvDortmundBundesliga · Germany | 2–1 | Bundesliga · Germany |
| 2024-09-28 | M'gladbachvUnion BerlinBundesliga · Germany | 1–0 | Bundesliga · Germany |
| 2024-09-21 | Union BerlinvHoffenheimBundesliga · Germany | 2–1 | Bundesliga · Germany |
| 2024-09-14 | RB LeipzigvUnion BerlinBundesliga · Germany | 0–0 | Bundesliga · Germany |
| 2024-08-30 | Union BerlinvSt PauliBundesliga · Germany | 1–0 | Bundesliga · Germany |
| 2024-08-24 | MainzvUnion BerlinBundesliga · Germany | 1–1 | Bundesliga · Germany |
| 2024-05-18 | Union BerlinvFreiburgBundesliga · Germany | 2–1 | Bundesliga · Germany |
| 2024-05-11 | FC KolnvUnion BerlinBundesliga · Germany | 3–2 | Bundesliga · Germany |
| 2024-05-05 | Union BerlinvBochumBundesliga · Germany | 3–4 | Bundesliga · Germany |
| 2024-04-28 | M'gladbachvUnion BerlinBundesliga · Germany | 0–0 | Bundesliga · Germany |
| 2024-04-20 | Union BerlinvBayern MunichBundesliga · Germany | 1–5 | Bundesliga · Germany |
| 2024-04-12 | AugsburgvUnion BerlinBundesliga · Germany | 2–0 | Bundesliga · Germany |
| 2024-04-06 | Union BerlinvLeverkusenBundesliga · Germany | 0–1 | Bundesliga · Germany |
| 2024-03-30 | Ein FrankfurtvUnion BerlinBundesliga · Germany | 0–0 | Bundesliga · Germany |
| 2024-03-16 | Union BerlinvWerder BremenBundesliga · Germany | 2–1 | Bundesliga · Germany |
| 2024-03-08 | StuttgartvUnion BerlinBundesliga · Germany | 2–0 | Bundesliga · Germany |
| 2024-03-02 | Union BerlinvDortmundBundesliga · Germany | 0–2 | Bundesliga · Germany |
| 2024-02-24 | Union BerlinvHeidenheimBundesliga · Germany | 2–2 | Bundesliga · Germany |
| 2024-02-17 | HoffenheimvUnion BerlinBundesliga · Germany | 0–1 | Bundesliga · Germany |
| 2024-02-10 | Union BerlinvWolfsburgBundesliga · Germany | 1–0 | Bundesliga · Germany |
| 2024-02-07 | MainzvUnion BerlinBundesliga · Germany | 1–1 | Bundesliga · Germany |
| 2024-02-04 | RB LeipzigvUnion BerlinBundesliga · Germany | 2–0 | Bundesliga · Germany |
| 2024-01-28 | Union BerlinvDarmstadtBundesliga · Germany | 1–0 | Bundesliga · Germany |
| 2024-01-24 | Bayern MunichvUnion BerlinBundesliga · Germany | 1–0 | Bundesliga · Germany |
| 2024-01-13 | FreiburgvUnion BerlinBundesliga · Germany | 0–0 | Bundesliga · Germany |