| 2012-12-22 | ValladolidvBarcelonaLa Liga · Spain | 1–3 | La Liga · Spain |
| 2012-12-16 | BarcelonavAth MadridLa Liga · Spain | 4–1 | La Liga · Spain |
| 2012-12-09 | BetisvBarcelonaLa Liga · Spain | 1–2 | La Liga · Spain |
| 2012-12-01 | BarcelonavAth BilbaoLa Liga · Spain | 5–1 | La Liga · Spain |
| 2012-11-25 | LevantevBarcelonaLa Liga · Spain | 0–4 | La Liga · Spain |
| 2012-11-17 | BarcelonavZaragozaLa Liga · Spain | 3–1 | La Liga · Spain |
| 2012-11-11 | MallorcavBarcelonaLa Liga · Spain | 2–4 | La Liga · Spain |
| 2012-11-03 | BarcelonavCeltaLa Liga · Spain | 3–1 | La Liga · Spain |
| 2012-10-27 | VallecanovBarcelonaLa Liga · Spain | 0–5 | La Liga · Spain |
| 2012-10-20 | La CorunavBarcelonaLa Liga · Spain | 4–5 | La Liga · Spain |
| 2012-10-07 | BarcelonavReal MadridLa Liga · Spain | 2–2 | La Liga · Spain |
| 2012-09-29 | SevillavBarcelonaLa Liga · Spain | 2–3 | La Liga · Spain |
| 2012-09-22 | BarcelonavGranadaLa Liga · Spain | 2–0 | La Liga · Spain |
| 2012-09-15 | GetafevBarcelonaLa Liga · Spain | 1–4 | La Liga · Spain |
| 2012-09-02 | BarcelonavValenciaLa Liga · Spain | 1–0 | La Liga · Spain |
| 2012-08-26 | OsasunavBarcelonaLa Liga · Spain | 1–2 | La Liga · Spain |
| 2012-08-19 | BarcelonavSociedadLa Liga · Spain | 5–1 | La Liga · Spain |
| 2012-05-12 | BetisvBarcelonaLa Liga · Spain | 2–2 | La Liga · Spain |
| 2012-05-05 | BarcelonavEspanolLa Liga · Spain | 4–0 | La Liga · Spain |
| 2012-05-02 | BarcelonavMalagaLa Liga · Spain | 4–1 | La Liga · Spain |
| 2012-04-29 | VallecanovBarcelonaLa Liga · Spain | 0–7 | La Liga · Spain |
| 2012-04-21 | BarcelonavReal MadridLa Liga · Spain | 1–2 | La Liga · Spain |
| 2012-04-14 | LevantevBarcelonaLa Liga · Spain | 1–2 | La Liga · Spain |
| 2012-04-10 | BarcelonavGetafeLa Liga · Spain | 4–0 | La Liga · Spain |
| 2012-04-07 | ZaragozavBarcelonaLa Liga · Spain | 1–4 | La Liga · Spain |
| 2012-03-31 | BarcelonavAth BilbaoLa Liga · Spain | 2–0 | La Liga · Spain |
| 2012-03-24 | MallorcavBarcelonaLa Liga · Spain | 0–2 | La Liga · Spain |
| 2012-03-20 | BarcelonavGranadaLa Liga · Spain | 5–3 | La Liga · Spain |
| 2012-03-17 | SevillavBarcelonaLa Liga · Spain | 0–2 | La Liga · Spain |
| 2012-03-11 | SantandervBarcelonaLa Liga · Spain | 0–2 | La Liga · Spain |
| 2012-03-03 | BarcelonavSp GijonLa Liga · Spain | 3–1 | La Liga · Spain |
| 2012-02-26 | Ath MadridvBarcelonaLa Liga · Spain | 1–2 | La Liga · Spain |
| 2012-02-19 | BarcelonavValenciaLa Liga · Spain | 5–1 | La Liga · Spain |
| 2012-02-11 | OsasunavBarcelonaLa Liga · Spain | 3–2 | La Liga · Spain |
| 2012-02-04 | BarcelonavSociedadLa Liga · Spain | 2–1 | La Liga · Spain |
| 2012-01-28 | VillarrealvBarcelonaLa Liga · Spain | 0–0 | La Liga · Spain |
| 2012-01-22 | MalagavBarcelonaLa Liga · Spain | 1–4 | La Liga · Spain |
| 2012-01-15 | BarcelonavBetisLa Liga · Spain | 4–2 | La Liga · Spain |
| 2012-01-08 | EspanolvBarcelonaLa Liga · Spain | 1–1 | La Liga · Spain |