| 2006-12-21 | BarcelonavAth MadridLa Liga · Spain | 1–1 | La Liga · Spain |
| 2006-12-09 | BarcelonavSociedadLa Liga · Spain | 1–0 | La Liga · Spain |
| 2006-12-02 | LevantevBarcelonaLa Liga · Spain | 1–1 | La Liga · Spain |
| 2006-11-25 | BarcelonavVillarrealLa Liga · Spain | 4–0 | La Liga · Spain |
| 2006-11-19 | MallorcavBarcelonaLa Liga · Spain | 1–4 | La Liga · Spain |
| 2006-11-12 | BarcelonavZaragozaLa Liga · Spain | 3–1 | La Liga · Spain |
| 2006-11-04 | La CorunavBarcelonaLa Liga · Spain | 1–1 | La Liga · Spain |
| 2006-10-28 | BarcelonavRecreativoLa Liga · Spain | 3–0 | La Liga · Spain |
| 2006-10-22 | Real MadridvBarcelonaLa Liga · Spain | 2–0 | La Liga · Spain |
| 2006-10-15 | BarcelonavSevillaLa Liga · Spain | 3–1 | La Liga · Spain |
| 2006-09-30 | Ath BilbaovBarcelonaLa Liga · Spain | 1–3 | La Liga · Spain |
| 2006-09-24 | BarcelonavValenciaLa Liga · Spain | 1–1 | La Liga · Spain |
| 2006-09-17 | SantandervBarcelonaLa Liga · Spain | 0–3 | La Liga · Spain |
| 2006-09-09 | BarcelonavOsasunaLa Liga · Spain | 3–0 | La Liga · Spain |
| 2006-08-28 | CeltavBarcelonaLa Liga · Spain | 2–3 | La Liga · Spain |
| 2006-05-20 | Ath BilbaovBarcelonaLa Liga · Spain | 3–1 | La Liga · Spain |
| 2006-05-13 | SevillavBarcelonaLa Liga · Spain | 3–2 | La Liga · Spain |
| 2006-05-06 | BarcelonavEspanolLa Liga · Spain | 2–0 | La Liga · Spain |
| 2006-05-03 | CeltavBarcelonaLa Liga · Spain | 0–1 | La Liga · Spain |
| 2006-04-29 | BarcelonavCadizLa Liga · Spain | 1–0 | La Liga · Spain |
| 2006-04-14 | BarcelonavVillarrealLa Liga · Spain | 1–0 | La Liga · Spain |
| 2006-04-09 | SantandervBarcelonaLa Liga · Spain | 2–2 | La Liga · Spain |
| 2006-04-01 | BarcelonavReal MadridLa Liga · Spain | 1–1 | La Liga · Spain |
| 2006-03-25 | MalagavBarcelonaLa Liga · Spain | 0–0 | La Liga · Spain |
| 2006-03-21 | BarcelonavGetafeLa Liga · Spain | 3–1 | La Liga · Spain |
| 2006-03-18 | SociedadvBarcelonaLa Liga · Spain | 0–2 | La Liga · Spain |
| 2006-03-12 | OsasunavBarcelonaLa Liga · Spain | 2–1 | La Liga · Spain |
| 2006-03-04 | BarcelonavLa CorunaLa Liga · Spain | 3–2 | La Liga · Spain |
| 2006-02-25 | ZaragozavBarcelonaLa Liga · Spain | 0–2 | La Liga · Spain |
| 2006-02-18 | BarcelonavBetisLa Liga · Spain | 5–1 | La Liga · Spain |
| 2006-02-12 | ValenciavBarcelonaLa Liga · Spain | 1–0 | La Liga · Spain |
| 2006-02-05 | BarcelonavAth MadridLa Liga · Spain | 1–3 | La Liga · Spain |
| 2006-01-29 | MallorcavBarcelonaLa Liga · Spain | 0–3 | La Liga · Spain |
| 2006-01-22 | BarcelonavAlavesLa Liga · Spain | 2–0 | La Liga · Spain |
| 2006-01-15 | BarcelonavAth BilbaoLa Liga · Spain | 2–1 | La Liga · Spain |
| 2006-01-07 | EspanolvBarcelonaLa Liga · Spain | 1–2 | La Liga · Spain |