| 1999-12-22 | VallecanovBarcelonaLa Liga · Spain | 1–1 | La Liga · Spain |
| 1999-12-19 | BarcelonavAth MadridLa Liga · Spain | 2–1 | La Liga · Spain |
| 1999-12-11 | SevillavBarcelonaLa Liga · Spain | 3–2 | La Liga · Spain |
| 1999-12-04 | BarcelonavOviedoLa Liga · Spain | 3–2 | La Liga · Spain |
| 1999-11-28 | MallorcavBarcelonaLa Liga · Spain | 3–2 | La Liga · Spain |
| 1999-11-20 | ValenciavBarcelonaLa Liga · Spain | 3–1 | La Liga · Spain |
| 1999-11-07 | BarcelonavMalagaLa Liga · Spain | 1–2 | La Liga · Spain |
| 1999-10-30 | La CorunavBarcelonaLa Liga · Spain | 2–1 | La Liga · Spain |
| 1999-10-23 | BarcelonavAth BilbaoLa Liga · Spain | 4–0 | La Liga · Spain |
| 1999-10-16 | NumanciavBarcelonaLa Liga · Spain | 3–3 | La Liga · Spain |
| 1999-10-13 | BarcelonavReal MadridLa Liga · Spain | 2–2 | La Liga · Spain |
| 1999-10-02 | ValladolidvBarcelonaLa Liga · Spain | 0–2 | La Liga · Spain |
| 1999-09-25 | BarcelonavBetisLa Liga · Spain | 4–1 | La Liga · Spain |
| 1999-09-18 | AlavesvBarcelonaLa Liga · Spain | 2–1 | La Liga · Spain |
| 1999-09-11 | BarcelonavEspanolLa Liga · Spain | 3–0 | La Liga · Spain |
| 1999-08-29 | SantandervBarcelonaLa Liga · Spain | 1–2 | La Liga · Spain |
| 1999-08-22 | BarcelonavZaragozaLa Liga · Spain | 2–0 | La Liga · Spain |
| 1999-06-20 | ZaragozavBarcelonaLa Liga · Spain | 2–0 | La Liga · Spain |
| 1999-06-13 | BarcelonavBetisLa Liga · Spain | 4–1 | La Liga · Spain |
| 1999-05-29 | Ath BilbaovBarcelonaLa Liga · Spain | 1–3 | La Liga · Spain |
| 1999-05-22 | AlavesvBarcelonaLa Liga · Spain | 1–4 | La Liga · Spain |
| 1999-05-15 | BarcelonavValladolidLa Liga · Spain | 1–1 | La Liga · Spain |
| 1999-05-09 | VillarealvBarcelonaLa Liga · Spain | 2–3 | La Liga · Spain |
| 1999-05-02 | BarcelonavLa CorunaLa Liga · Spain | 4–0 | La Liga · Spain |
| 1999-04-25 | Ath MadridvBarcelonaLa Liga · Spain | 1–1 | La Liga · Spain |
| 1999-04-17 | BarcelonavMallorcaLa Liga · Spain | 2–1 | La Liga · Spain |
| 1999-04-10 | TenerifevBarcelonaLa Liga · Spain | 2–3 | La Liga · Spain |
| 1999-04-04 | BarcelonavOviedoLa Liga · Spain | 3–1 | La Liga · Spain |
| 1999-03-21 | SociedadvBarcelonaLa Liga · Spain | 0–2 | La Liga · Spain |
| 1999-03-14 | BarcelonavEspanolLa Liga · Spain | 3–0 | La Liga · Spain |
| 1999-03-07 | SalamancavBarcelonaLa Liga · Spain | 1–4 | La Liga · Spain |
| 1999-02-27 | BarcelonavValenciaLa Liga · Spain | 2–4 | La Liga · Spain |
| 1999-02-21 | CeltavBarcelonaLa Liga · Spain | 0–0 | La Liga · Spain |
| 1999-02-14 | BarcelonavReal MadridLa Liga · Spain | 3–0 | La Liga · Spain |
| 1999-02-07 | ExtremaduravBarcelonaLa Liga · Spain | 1–2 | La Liga · Spain |
| 1999-01-31 | BarcelonavSantanderLa Liga · Spain | 3–2 | La Liga · Spain |
| 1999-01-24 | BarcelonavZaragozaLa Liga · Spain | 3–1 | La Liga · Spain |
| 1999-01-17 | BetisvBarcelonaLa Liga · Spain | 0–3 | La Liga · Spain |
| 1999-01-09 | BarcelonavAth BilbaoLa Liga · Spain | 4–2 | La Liga · Spain |
| 1999-01-03 | BarcelonavAlavesLa Liga · Spain | 7–1 | La Liga · Spain |