| 2014-02-22 | AarauvZurichSuper League · Switzerland | 1–2 | Super League · Switzerland |
| 2014-02-22 | FreiburgvAugsburgBundesliga · Germany | 2–4 | Bundesliga · Germany |
| 2014-02-22 | Las PalmasvGironaLa Liga 2 · Spain | 2–1 | La Liga 2 · Spain |
| 2014-02-22 | LevadeiakosvAsteras TripolisSuper League · Greece | 3–1 | Super League · Greece |
| 2014-02-22 | KidderminstervBraintree TownNational League · England | 2–2 | National League · England |
| 2014-02-22 | NovaravRegginaSerie B · Italy | 1–0 | Serie B · Italy |
| 2014-02-22 | SK RapidvGrodigBundesliga · Austria | 0–0 | Bundesliga · Austria |
| 2014-02-22 | ZwollevHeraclesEredivisie · Netherlands | 1–1 | Eredivisie · Netherlands |
| 2014-02-22 | St JohnstonevInverness CPremiership · Scotland | 0–1 | Premiership · Scotland |
| 2014-02-22 | Rio AvevSp LisbonPrimeira Liga · Portugal | 1–2 | Primeira Liga · Portugal |
| 2014-02-22 | LeicestervIpswichChampionship · England | 3–0 | Championship · England |
| 2014-02-22 | CarlislevRotherhamLeague One · England | 1–2 | League One · England |
| 2014-02-22 | GalatasarayvBesiktasSüper Lig · Turkey | 1–0 | Süper Lig · Turkey |
| 2014-02-22 | ColchestervPrestonLeague One · England | 1–2 | League One · England |
| 2014-02-22 | KortrijkvBergenPro League · Belgium | 1–2 | Pro League · Belgium |
| 2014-02-22 | ElginvStirlingLeague Two · Scotland | 2–3 | League Two · Scotland |
| 2014-02-22 | OtelulvPanduriiSuperliga · Romania | 1–0 | Superliga · Romania |
| 2014-02-22 | ReadingvBlackburnChampionship · England | 0–1 | Championship · England |
| 2014-02-22 | LincolnvChesterNational League · England | 1–1 | National League · England |
| 2014-02-22 | WycombevChesterfieldLeague Two · England | 1–0 | League Two · England |
| 2014-02-22 | Barcelona BvRecreativoLa Liga 2 · Spain | 0–1 | La Liga 2 · Spain |
| 2014-02-22 | All BoysvOlimpo Bahia BlancaLiga Profesional · Argentina | 1–0 | Liga Profesional · Argentina |
| 2014-02-22 | Sheffield UnitedvBristol CityLeague One · England | 3–0 | League One · England |
| 2014-02-22 | ThunvSionSuper League · Switzerland | 3–1 | Super League · Switzerland |
| 2014-02-22 | Gornik Z.vLegiaEkstraklasa · Poland | 0–3 | Ekstraklasa · Poland |
| 2014-02-22 | Nuneaton TownvLutonNational League · England | 0–5 | National League · England |
| 2014-02-22 | Queens ParkvAnnan AthleticLeague Two · Scotland | 0–1 | League Two · Scotland |
| 2014-02-22 | Forest GreenvSouthportNational League · England | 3–1 | National League · England |
| 2014-02-22 | NorthamptonvHartlepoolLeague Two · England | 2–0 | League Two · England |
| 2014-02-22 | OostendevLiersePro League · Belgium | 3–2 | Pro League · Belgium |
| 2014-02-22 | Port ValevCreweLeague One · England | 1–3 | League One · England |
| 2014-02-22 | DunfermlinevAyrLeague One · Scotland | 3–0 | League One · Scotland |
| 2014-02-22 | FalkirkvQueen of SthChampionship · Scotland | 1–0 | Championship · Scotland |
| 2014-02-22 | WolfsburgvLeverkusenBundesliga · Germany | 3–1 | Bundesliga · Germany |
| 2014-02-22 | TernanavSienaSerie B · Italy | 2–2 | Serie B · Italy |
| 2014-02-22 | BarnsleyvMillwallChampionship · England | 1–0 | Championship · England |
| 2014-02-22 | BrechinvStranraerLeague One · Scotland | 1–3 | League One · Scotland |
| 2014-02-22 | Real MadridvElcheLa Liga · Spain | 3–0 | La Liga · Spain |
| 2014-02-22 | StevenagevPeterboroLeague One · England | 0–1 | League One · England |
| 2014-02-22 | KarlsruhevSandhausen2. Bundesliga · Germany | 2–1 | 2. Bundesliga · Germany |
| 2014-02-22 | BurnleyvNott'm ForestChampionship · England | 3–1 | Championship · England |
| 2014-02-22 | DumbartonvRaith RvsChampionship · Scotland | 3–3 | Championship · Scotland |
| 2014-02-22 | CambuurvRodaEredivisie · Netherlands | 1–0 | Eredivisie · Netherlands |
| 2014-02-22 | CharleroivWaregemPro League · Belgium | 3–2 | Pro League · Belgium |
| 2014-02-22 | ArsenalvSunderlandPremier League · England | 4–1 | Premier League · England |
| 2014-02-22 | AFC WimbledonvBuryLeague Two · England | 0–1 | League Two · England |
| 2014-02-22 | East StirlingvBerwickLeague Two · Scotland | 1–1 | League Two · Scotland |
| 2014-02-22 | HeartsvCelticPremiership · Scotland | 0–2 | Premiership · Scotland |
| 2014-02-22 | Albion RvsvPeterheadLeague Two · Scotland | 0–0 | League Two · Scotland |
| 2014-02-22 | Juve StabiavCittadellaSerie B · Italy | 1–1 | Serie B · Italy |