| 1966-04-17 |  Chilev BrazilCopa Bernardo O'Higgins | 0–1 | Copa Bernardo O'Higgins |
| 1965-11-21 | Brazilv Russiaplayed as Soviet UnionFriendly | 2–2 | Friendly |
| 1965-11-21 | Brazilv HungaryFriendly | 5–3 | Friendly |
| 1965-09-07 | Brazilv UruguayFriendly | 3–0 | Friendly |
| 1965-07-04 | Russiaplayed as Soviet UnionvBrazilFriendly | 0–3 | Friendly |
| 1965-06-30 |  SwedenvBrazilFriendly | 1–2 | Friendly |
| 1965-06-24 |  PortugalvBrazilFriendly | 0–0 | Friendly |
| 1965-06-17 |  AlgeriavBrazilFriendly | 0–3 | Friendly |
| 1965-06-09 | Brazilv ArgentinaFriendly | 0–0 | Friendly |
| 1965-06-06 | Brazilv GermanyFriendly | 2–0 | Friendly |
| 1965-06-02 | Brazilv BelgiumFriendly | 5–0 | Friendly |
| 1964-06-07 | BrazilvPortugalFriendly | 4–1 | Friendly |
| 1964-06-03 | BrazilvArgentinaFriendly | 0–3 | Friendly |
| 1964-05-30 | Brazilv EnglandFriendly | 5–1 | Friendly |
| 1963-05-19 |  IsraelvBrazilFriendly | 0–5 | Friendly |
| 1963-05-17 |  Egyptplayed as United Arab RepublicvBrazilFriendly | 0–1 | Friendly |
| 1963-05-12 |  ItalyvBrazilFriendly | 3–0 | Friendly |
| 1963-05-08 | EnglandvBrazilFriendly | 1–1 | Friendly |
| 1963-05-05 | GermanyvBrazilFriendly | 1–2 | Friendly |
| 1963-05-02 |  NetherlandsvBrazilFriendly | 1–0 | Friendly |
| 1963-04-28 |  FrancevBrazilFriendly | 2–3 | Friendly |
| 1963-04-24 | BelgiumvBrazilFriendly | 5–1 | Friendly |
| 1963-04-21 | PortugalvBrazilFriendly | 1–0 | Friendly |
| 1963-04-16 | BrazilvArgentinaCopa Roca | 5–2 | Copa Roca |
| 1963-04-13 | BrazilvArgentinaCopa Roca | 2–3 | Copa Roca |
| 1963-03-31 |  BoliviavBrazilCopa América | 5–4 | Copa América |
| 1963-03-27 | Brazilv EcuadorCopa América | 2–2 | Copa América |
| 1963-03-24 | ArgentinavBrazilCopa América | 3–0 | Copa América |
| 1963-03-17 | Brazilv ParaguayCopa América | 0–2 | Copa América |
| 1963-03-14 | Brazilv ColombiaCopa América | 5–1 | Copa América |
| 1963-03-10 | Brazilv PeruCopa América | 1–0 | Copa América |
| 1963-03-03 | ParaguayvBrazilFriendly | 2–2 | Friendly |
| 1962-06-17 | BrazilvCzechoslovakiaFIFA World Cup | 3–1 | FIFA World Cup |
| 1962-06-13 | ChilevBrazilFIFA World Cup | 2–4 | FIFA World Cup |
| 1962-06-10 | BrazilvEnglandFIFA World Cup | 3–1 | FIFA World Cup |
| 1962-06-06 | Brazilv SpainFIFA World Cup | 2–1 | FIFA World Cup |
| 1962-06-02 | BrazilvCzechoslovakiaFIFA World Cup | 0–0 | FIFA World Cup |
| 1962-05-30 | Brazilv MexicoFIFA World Cup | 2–0 | FIFA World Cup |
| 1962-05-16 | Brazilv WalesFriendly | 3–1 | Friendly |
| 1962-05-12 | BrazilvWalesFriendly | 3–1 | Friendly |
| 1962-05-09 | BrazilvPortugalFriendly | 1–0 | Friendly |
| 1962-05-06 | BrazilvPortugalFriendly | 2–1 | Friendly |
| 1962-04-24 | BrazilvParaguayCopa Oswaldo Cruz | 4–0 | Copa Oswaldo Cruz |
| 1962-04-21 | BrazilvParaguayCopa Oswaldo Cruz | 6–0 | Copa Oswaldo Cruz |
| 1961-06-29 | BrazilvParaguayFriendly | 3–2 | Friendly |
| 1961-05-11 | ChilevBrazilCopa Bernardo O'Higgins | 0–1 | Copa Bernardo O'Higgins |
| 1961-05-07 | ChilevBrazilCopa Bernardo O'Higgins | 1–2 | Copa Bernardo O'Higgins |
| 1961-05-03 | ParaguayvBrazilCopa Oswaldo Cruz | 2–3 | Copa Oswaldo Cruz |
| 1961-04-30 | ParaguayvBrazilCopa Oswaldo Cruz | 0–2 | Copa Oswaldo Cruz |
| 1960-07-12 | BrazilvArgentinaAtlantic Cup | 5–1 | Atlantic Cup |