| 1971-03-17 |  Spainv FranceFriendly | 2–2 | Friendly |
| 1971-02-20 |  ItalyvSpainFriendly | 1–2 | Friendly |
| 1970-11-11 | Spainv Northern IrelandUEFA Euro qualification | 3–0 | UEFA Euro qualification |
| 1970-10-28 | Spainv GreeceFriendly | 2–1 | Friendly |
| 1970-04-22 |  SwitzerlandvSpainFriendly | 0–1 | Friendly |
| 1970-02-21 | SpainvItalyFriendly | 2–2 | Friendly |
| 1970-02-11 | Spainv GermanyFriendly | 2–0 | Friendly |
| 1969-10-15 | Spainv FinlandFIFA World Cup qualification | 6–0 | FIFA World Cup qualification |
| 1969-06-25 | FinlandvSpainFIFA World Cup qualification | 2–0 | FIFA World Cup qualification |
| 1969-04-30 | SpainvYugoslaviaFIFA World Cup qualification | 2–1 | FIFA World Cup qualification |
| 1969-04-23 | Spainv MexicoFriendly | 0–0 | Friendly |
| 1969-03-26 | SpainvSwitzerlandFriendly | 1–0 | Friendly |
| 1969-02-23 |  BelgiumvSpainFIFA World Cup qualification | 2–1 | FIFA World Cup qualification |
| 1968-12-11 | SpainvBelgiumFIFA World Cup qualification | 1–1 | FIFA World Cup qualification |
| 1968-10-27 | YugoslaviavSpainFIFA World Cup qualification | 0–0 | FIFA World Cup qualification |
| 1968-10-17 | FrancevSpainFriendly | 1–3 | Friendly |
| 1968-05-08 | Spainv EnglandUEFA Euro qualification | 1–2 | UEFA Euro qualification |
| 1968-05-02 |  SwedenvSpainFriendly | 1–1 | Friendly |
| 1968-04-03 | EnglandvSpainUEFA Euro qualification | 1–0 | UEFA Euro qualification |
| 1968-02-28 | SpainvSwedenFriendly | 3–1 | Friendly |
| 1967-10-22 | SpainvCzechoslovakiaUEFA Euro qualification | 2–1 | UEFA Euro qualification |
| 1967-10-01 | CzechoslovakiavSpainUEFA Euro qualification | 1–0 | UEFA Euro qualification |
| 1967-05-31 | Spainv TurkeyUEFA Euro qualification | 2–0 | UEFA Euro qualification |
| 1967-05-24 | EnglandvSpainFriendly | 2–0 | Friendly |
| 1967-02-01 | TurkeyvSpainUEFA Euro qualification | 0–0 | UEFA Euro qualification |
| 1966-12-07 | Spainv Republic of IrelandUEFA Euro qualification | 2–0 | UEFA Euro qualification |
| 1966-10-23 | Republic of IrelandvSpainUEFA Euro qualification | 0–0 | UEFA Euro qualification |
| 1966-07-20 | GermanyvSpainFIFA World Cup | 2–1 | FIFA World Cup |
| 1966-07-15 | SpainvSwitzerlandFIFA World Cup | 2–1 | FIFA World Cup |
| 1966-07-13 |  ArgentinavSpainFIFA World Cup | 2–1 | FIFA World Cup |
| 1966-06-23 | Spainv UruguayFriendly | 1–1 | Friendly |
| 1965-12-08 | SpainvEnglandFriendly | 0–2 | Friendly |
| 1965-11-10 | Republic of IrelandvSpainFIFA World Cup qualification | 0–1 | FIFA World Cup qualification |
| 1965-10-27 | SpainvRepublic of IrelandFIFA World Cup qualification | 4–1 | FIFA World Cup qualification |
| 1965-05-08 |  ScotlandvSpainFriendly | 0–0 | Friendly |
| 1965-05-05 | Republic of IrelandvSpainFIFA World Cup qualification | 1–0 | FIFA World Cup qualification |
| 1964-11-15 |  PortugalvSpainFriendly | 2–1 | Friendly |
| 1964-06-21 | Spainv Russiaplayed as Soviet UnionUEFA Euro | 2–1 | UEFA Euro |
| 1964-06-17 | Spainv HungaryUEFA Euro | 2–1 | UEFA Euro |
| 1964-04-08 | Republic of IrelandvSpainUEFA Euro qualification | 0–2 | UEFA Euro qualification |
| 1964-03-11 | SpainvRepublic of IrelandUEFA Euro qualification | 5–1 | UEFA Euro qualification |
| 1963-12-01 | SpainvBelgiumFriendly | 1–2 | Friendly |
| 1963-10-30 | Northern IrelandvSpainUEFA Euro qualification | 0–1 | UEFA Euro qualification |
| 1963-06-13 | SpainvScotlandFriendly | 2–6 | Friendly |
| 1963-05-30 | SpainvNorthern IrelandUEFA Euro qualification | 1–1 | UEFA Euro qualification |
| 1963-01-09 | SpainvFranceFriendly | 0–0 | Friendly |
| 1962-12-02 | BelgiumvSpainFriendly | 1–1 | Friendly |
| 1962-11-25 |  RomaniavSpainUEFA Euro qualification | 3–1 | UEFA Euro qualification |
| 1962-11-01 | SpainvRomaniaUEFA Euro qualification | 6–0 | UEFA Euro qualification |
| 1962-06-06 |  BrazilvSpainFIFA World Cup | 2–1 | FIFA World Cup |