| 2012-10-27 | Philadelphia UnionvNew York Red BullsMLS · United States | 0–3 | MLS · United States |
| 2012-10-25 | Sporting Kansas CityvPhiladelphia UnionMLS · United States | 2–1 | MLS · United States |
| 2012-10-21 | Houston DynamovPhiladelphia UnionMLS · United States | 3–1 | MLS · United States |
| 2012-10-07 | Philadelphia UnionvNew England RevolutionMLS · United States | 1–0 | MLS · United States |
| 2012-10-04 | Chicago FirevPhiladelphia UnionMLS · United States | 1–3 | MLS · United States |
| 2012-09-30 | Columbus CrewvPhiladelphia UnionMLS · United States | 3–2 | MLS · United States |
| 2012-09-23 | Philadelphia UnionvHouston DynamoMLS · United States | 3–1 | MLS · United States |
| 2012-09-21 | Philadelphia UnionvDC UnitedMLS · United States | 0–1 | MLS · United States |
| 2012-09-15 | Toronto FCvPhiladelphia UnionMLS · United States | 1–1 | MLS · United States |
| 2012-09-02 | New England RevolutionvPhiladelphia UnionMLS · United States | 0–0 | MLS · United States |
| 2012-08-30 | Philadelphia UnionvColumbus CrewMLS · United States | 1–2 | MLS · United States |
| 2012-08-25 | Philadelphia UnionvReal Salt LakeMLS · United States | 0–0 | MLS · United States |
| 2012-08-19 | DC UnitedvPhiladelphia UnionMLS · United States | 1–1 | MLS · United States |
| 2012-08-13 | Philadelphia UnionvChicago FireMLS · United States | 1–3 | MLS · United States |
| 2012-08-05 | CF MontrealvPhiladelphia UnionMLS · United States | 2–0 | MLS · United States |
| 2012-07-30 | Philadelphia UnionvNew England RevolutionMLS · United States | 2–1 | MLS · United States |
| 2012-07-21 | New York Red BullsvPhiladelphia UnionMLS · United States | 2–0 | MLS · United States |
| 2012-07-15 | Philadelphia UnionvCF MontrealMLS · United States | 2–1 | MLS · United States |
| 2012-07-08 | Philadelphia UnionvToronto FCMLS · United States | 3–0 | MLS · United States |
| 2012-07-05 | Los Angeles GalaxyvPhiladelphia UnionMLS · United States | 1–2 | MLS · United States |
| 2012-07-01 | Houston DynamovPhiladelphia UnionMLS · United States | 2–1 | MLS · United States |
| 2012-06-24 | Philadelphia UnionvSporting Kansas CityMLS · United States | 4–0 | MLS · United States |
| 2012-06-17 | Philadelphia UnionvDC UnitedMLS · United States | 0–1 | MLS · United States |
| 2012-05-26 | Toronto FCvPhiladelphia UnionMLS · United States | 1–0 | MLS · United States |
| 2012-05-20 | FC DallasvPhiladelphia UnionMLS · United States | 1–1 | MLS · United States |
| 2012-05-13 | Philadelphia UnionvNew York Red BullsMLS · United States | 2–3 | MLS · United States |
| 2012-05-05 | Seattle SoundersvPhiladelphia UnionMLS · United States | 1–0 | MLS · United States |
| 2012-04-29 | Philadelphia UnionvSan Jose EarthquakesMLS · United States | 1–2 | MLS · United States |
| 2012-04-22 | Chivas USAvPhiladelphia UnionMLS · United States | 0–1 | MLS · United States |
| 2012-04-14 | Philadelphia UnionvColumbus CrewMLS · United States | 1–0 | MLS · United States |
| 2012-03-31 | Philadelphia UnionvVancouver WhitecapsMLS · United States | 0–0 | MLS · United States |
| 2012-03-25 | Chicago FirevPhiladelphia UnionMLS · United States | 1–0 | MLS · United States |
| 2012-03-18 | Philadelphia UnionvColorado RapidsMLS · United States | 1–2 | MLS · United States |
| 2012-03-13 | Portland TimbersvPhiladelphia UnionMLS · United States | 3–1 | MLS · United States |