| 2010-03-09 | FiorentinavBayern MunichUEFA Champions League | 3–2 | UEFA Champions League |
| 2010-02-17 | Bayern MunichvFiorentinaUEFA Champions League | 2–1 | UEFA Champions League |
| 2009-12-09 | LiverpoolvFiorentinaUEFA Champions League | 1–2 | UEFA Champions League |
| 2009-11-24 | FiorentinavLyonUEFA Champions League | 1–0 | UEFA Champions League |
| 2009-11-04 | FiorentinavDebrecenUEFA Champions League | 5–2 | UEFA Champions League |
| 2009-10-20 | DebrecenvFiorentinaUEFA Champions League | 3–4 | UEFA Champions League |
| 2009-09-29 | FiorentinavLiverpoolUEFA Champions League | 2–0 | UEFA Champions League |
| 2009-09-16 | LyonvFiorentinaUEFA Champions League | 1–0 | UEFA Champions League |
| 2009-08-26 | FiorentinavSporting CPUEFA Champions League | 1–1 | UEFA Champions League |
| 2009-08-18 | Sporting CPvFiorentinaUEFA Champions League | 2–2 | UEFA Champions League |
| 2008-12-10 | Steaua BucureștivFiorentinaUEFA Champions League | 0–1 | UEFA Champions League |
| 2008-11-25 | FiorentinavLyonUEFA Champions League | 1–2 | UEFA Champions League |
| 2008-11-05 | FiorentinavBayern MunichUEFA Champions League | 1–1 | UEFA Champions League |
| 2008-10-21 | Bayern MunichvFiorentinaUEFA Champions League | 3–0 | UEFA Champions League |
| 2008-09-30 | FiorentinavSteaua BucureștiUEFA Champions League | 0–0 | UEFA Champions League |
| 2008-09-17 | LyonvFiorentinaUEFA Champions League | 2–2 | UEFA Champions League |
| 2008-08-27 | Slavia PraguevFiorentinaUEFA Champions League | 0–0 | UEFA Champions League |
| 2008-08-12 | FiorentinavSlavia PragueUEFA Champions League | 2–0 | UEFA Champions League |
| 2000-03-21 | FiorentinavBordeauxUEFA Champions League | 3–3 | UEFA Champions League |
| 2000-03-15 | Manchester UnitedvFiorentinaUEFA Champions League | 3–1 | UEFA Champions League |
| 2000-03-07 | ValenciavFiorentinaUEFA Champions League | 2–0 | UEFA Champions League |
| 2000-03-01 | FiorentinavValenciaUEFA Champions League | 1–0 | UEFA Champions League |
| 1999-12-08 | BordeauxvFiorentinaUEFA Champions League | 0–0 | UEFA Champions League |
| 1999-11-23 | FiorentinavManchester UnitedUEFA Champions League | 2–0 | UEFA Champions League |
| 1999-11-02 | FiorentinavBarcelonaUEFA Champions League | 3–3 | UEFA Champions League |
| 1999-10-27 | ArsenalvFiorentinaUEFA Champions League | 0–1 | UEFA Champions League |
| 1999-10-19 | FiorentinavAIKUEFA Champions League | 3–0 | UEFA Champions League |
| 1999-09-29 | AIKvFiorentinaUEFA Champions League | 0–0 | UEFA Champions League |
| 1999-09-22 | BarcelonavFiorentinaUEFA Champions League | 4–2 | UEFA Champions League |
| 1999-09-14 | FiorentinavArsenalUEFA Champions League | 0–0 | UEFA Champions League |
| 1999-08-25 | Widzew ŁódźvFiorentinaUEFA Champions League | 0–2 | UEFA Champions League |
| 1999-08-11 | FiorentinavWidzew ŁódźUEFA Champions League | 3–1 | UEFA Champions League |
| 1970-03-18 | FiorentinavCelticUEFA Champions League | 1–0 | UEFA Champions League |
| 1970-03-04 | CelticvFiorentinaUEFA Champions League | 3–0 | UEFA Champions League |
| 1969-11-26 | FiorentinavDynamo KyivUEFA Champions League | 0–0 | UEFA Champions League |
| 1969-11-12 | Dynamo KyivvFiorentinaUEFA Champions League | 1–2 | UEFA Champions League |
| 1969-09-17 | FiorentinavÖsterUEFA Champions League | 1–0 | UEFA Champions League |
| 1957-05-30 | Real MadridvFiorentinaUEFA Champions League | 2–0 | UEFA Champions League |