| 2012-12-22 | ValladolidvBarcelonaLa Liga · Spain | 1–3 | La Liga · Spain |
| 2012-12-17 | La CorunavValladolidLa Liga · Spain | 0–0 | La Liga · Spain |
| 2012-12-08 | ValladolidvReal MadridLa Liga · Spain | 2–3 | La Liga · Spain |
| 2012-12-03 | SevillavValladolidLa Liga · Spain | 1–2 | La Liga · Spain |
| 2012-11-24 | ValladolidvGranadaLa Liga · Spain | 1–0 | La Liga · Spain |
| 2012-11-18 | GetafevValladolidLa Liga · Spain | 2–1 | La Liga · Spain |
| 2012-11-11 | ValladolidvValenciaLa Liga · Spain | 1–1 | La Liga · Spain |
| 2012-11-04 | OsasunavValladolidLa Liga · Spain | 0–1 | La Liga · Spain |
| 2012-10-29 | ValladolidvSociedadLa Liga · Spain | 2–2 | La Liga · Spain |
| 2012-10-20 | MalagavValladolidLa Liga · Spain | 2–1 | La Liga · Spain |
| 2012-10-06 | ValladolidvEspanolLa Liga · Spain | 1–1 | La Liga · Spain |
| 2012-09-30 | ValladolidvVallecanoLa Liga · Spain | 6–1 | La Liga · Spain |
| 2012-09-23 | Ath MadridvValladolidLa Liga · Spain | 2–1 | La Liga · Spain |
| 2012-09-17 | ValladolidvBetisLa Liga · Spain | 0–1 | La Liga · Spain |
| 2012-09-02 | Ath BilbaovValladolidLa Liga · Spain | 2–0 | La Liga · Spain |
| 2012-08-27 | ValladolidvLevanteLa Liga · Spain | 2–0 | La Liga · Spain |
| 2012-08-20 | ZaragozavValladolidLa Liga · Spain | 0–1 | La Liga · Spain |