| 1999-12-22 | Ath MadridvOviedoLa Liga · Spain | 5–0 | La Liga · Spain |
| 1999-12-19 | BarcelonavAth MadridLa Liga · Spain | 2–1 | La Liga · Spain |
| 1999-12-12 | Ath MadridvValenciaLa Liga · Spain | 1–2 | La Liga · Spain |
| 1999-12-05 | MalagavAth MadridLa Liga · Spain | 2–3 | La Liga · Spain |
| 1999-11-28 | Ath MadridvLa CorunaLa Liga · Spain | 1–3 | La Liga · Spain |
| 1999-11-20 | Ath BilbaovAth MadridLa Liga · Spain | 4–2 | La Liga · Spain |
| 1999-11-07 | Ath MadridvNumanciaLa Liga · Spain | 2–2 | La Liga · Spain |
| 1999-10-30 | Real MadridvAth MadridLa Liga · Spain | 1–3 | La Liga · Spain |
| 1999-10-24 | Ath MadridvValladolidLa Liga · Spain | 3–1 | La Liga · Spain |
| 1999-10-17 | BetisvAth MadridLa Liga · Spain | 2–1 | La Liga · Spain |
| 1999-10-11 | Ath MadridvAlavesLa Liga · Spain | 1–0 | La Liga · Spain |
| 1999-10-03 | EspanolvAth MadridLa Liga · Spain | 3–1 | La Liga · Spain |
| 1999-09-26 | Ath MadridvSantanderLa Liga · Spain | 2–0 | La Liga · Spain |
| 1999-09-19 | ZaragozavAth MadridLa Liga · Spain | 1–1 | La Liga · Spain |
| 1999-09-12 | Ath MadridvCeltaLa Liga · Spain | 1–2 | La Liga · Spain |
| 1999-08-28 | SociedadvAth MadridLa Liga · Spain | 4–1 | La Liga · Spain |
| 1999-08-22 | Ath MadridvVallecanoLa Liga · Spain | 0–2 | La Liga · Spain |
| 1999-06-20 | CeltavAth MadridLa Liga · Spain | 0–1 | La Liga · Spain |
| 1999-06-12 | Ath MadridvReal MadridLa Liga · Spain | 3–1 | La Liga · Spain |
| 1999-05-30 | ExtremaduravAth MadridLa Liga · Spain | 2–1 | La Liga · Spain |
| 1999-05-23 | Ath MadridvSantanderLa Liga · Spain | 1–1 | La Liga · Spain |
| 1999-05-16 | ZaragozavAth MadridLa Liga · Spain | 2–0 | La Liga · Spain |
| 1999-05-09 | Ath MadridvBetisLa Liga · Spain | 2–3 | La Liga · Spain |
| 1999-05-02 | Ath BilbaovAth MadridLa Liga · Spain | 1–2 | La Liga · Spain |
| 1999-04-25 | Ath MadridvBarcelonaLa Liga · Spain | 1–1 | La Liga · Spain |
| 1999-04-17 | ValladolidvAth MadridLa Liga · Spain | 1–0 | La Liga · Spain |
| 1999-04-11 | Ath MadridvVillarealLa Liga · Spain | 2–2 | La Liga · Spain |
| 1999-04-03 | La CorunavAth MadridLa Liga · Spain | 1–1 | La Liga · Spain |
| 1999-03-21 | AlavesvAth MadridLa Liga · Spain | 2–0 | La Liga · Spain |
| 1999-03-13 | Ath MadridvMallorcaLa Liga · Spain | 1–2 | La Liga · Spain |
| 1999-03-07 | TenerifevAth MadridLa Liga · Spain | 1–0 | La Liga · Spain |
| 1999-02-27 | Ath MadridvOviedoLa Liga · Spain | 0–0 | La Liga · Spain |
| 1999-02-21 | SociedadvAth MadridLa Liga · Spain | 3–2 | La Liga · Spain |
| 1999-02-13 | Ath MadridvEspanolLa Liga · Spain | 1–2 | La Liga · Spain |
| 1999-02-07 | SalamancavAth MadridLa Liga · Spain | 2–1 | La Liga · Spain |
| 1999-01-30 | Ath MadridvValenciaLa Liga · Spain | 1–2 | La Liga · Spain |
| 1999-01-24 | Ath MadridvCeltaLa Liga · Spain | 2–1 | La Liga · Spain |
| 1999-01-17 | Real MadridvAth MadridLa Liga · Spain | 4–2 | La Liga · Spain |
| 1999-01-10 | Ath MadridvExtremaduraLa Liga · Spain | 5–0 | La Liga · Spain |
| 1999-01-03 | SantandervAth MadridLa Liga · Spain | 2–3 | La Liga · Spain |