| 2013-05-19 | SienavMilanSerie A · Italy | 1–2 | Serie A · Italy |
| 2013-05-12 | NapolivSienaSerie A · Italy | 2–1 | Serie A · Italy |
| 2013-05-08 | SienavFiorentinaSerie A · Italy | 0–1 | Serie A · Italy |
| 2013-05-05 | CataniavSienaSerie A · Italy | 3–0 | Serie A · Italy |
| 2013-04-28 | RomavSienaSerie A · Italy | 4–0 | Serie A · Italy |
| 2013-04-21 | SienavChievoSerie A · Italy | 0–1 | Serie A · Italy |
| 2013-04-13 | PescaravSienaSerie A · Italy | 2–3 | Serie A · Italy |
| 2013-04-07 | SienavParmaSerie A · Italy | 0–0 | Serie A · Italy |
| 2013-03-30 | GenoavSienaSerie A · Italy | 2–2 | Serie A · Italy |
| 2013-03-17 | SienavCagliariSerie A · Italy | 0–0 | Serie A · Italy |
| 2013-03-10 | PalermovSienaSerie A · Italy | 1–2 | Serie A · Italy |
| 2013-03-03 | SienavAtalantaSerie A · Italy | 0–2 | Serie A · Italy |
| 2013-02-24 | JuventusvSienaSerie A · Italy | 3–0 | Serie A · Italy |
| 2013-02-18 | SienavLazioSerie A · Italy | 3–0 | Serie A · Italy |
| 2013-02-10 | BolognavSienaSerie A · Italy | 1–1 | Serie A · Italy |
| 2013-02-03 | SienavInterSerie A · Italy | 3–1 | Serie A · Italy |
| 2013-01-27 | UdinesevSienaSerie A · Italy | 1–0 | Serie A · Italy |
| 2013-01-20 | SienavSampdoriaSerie A · Italy | 1–0 | Serie A · Italy |
| 2013-01-13 | TorinovSienaSerie A · Italy | 3–2 | Serie A · Italy |
| 2013-01-06 | MilanvSienaSerie A · Italy | 2–1 | Serie A · Italy |