| 2022-11-12 | NapolivUdineseSerie A · Italy | 3–2 | Serie A · Italy |
| 2022-11-08 | NapolivEmpoliSerie A · Italy | 2–0 | Serie A · Italy |
| 2022-11-05 | AtalantavNapoliSerie A · Italy | 1–2 | Serie A · Italy |
| 2022-10-29 | NapolivSassuoloSerie A · Italy | 4–0 | Serie A · Italy |
| 2022-10-23 | RomavNapoliSerie A · Italy | 0–1 | Serie A · Italy |
| 2022-10-16 | NapolivBolognaSerie A · Italy | 3–2 | Serie A · Italy |
| 2022-10-09 | CremonesevNapoliSerie A · Italy | 1–4 | Serie A · Italy |
| 2022-10-01 | NapolivTorinoSerie A · Italy | 3–1 | Serie A · Italy |
| 2022-09-18 | MilanvNapoliSerie A · Italy | 1–2 | Serie A · Italy |
| 2022-09-10 | NapolivSpeziaSerie A · Italy | 1–0 | Serie A · Italy |
| 2022-09-03 | LaziovNapoliSerie A · Italy | 1–2 | Serie A · Italy |
| 2022-08-31 | NapolivLecceSerie A · Italy | 1–1 | Serie A · Italy |
| 2022-08-28 | FiorentinavNapoliSerie A · Italy | 0–0 | Serie A · Italy |
| 2022-08-21 | NapolivMonzaSerie A · Italy | 4–0 | Serie A · Italy |
| 2022-08-15 | VeronavNapoliSerie A · Italy | 2–5 | Serie A · Italy |
| 2022-05-22 | SpeziavNapoliSerie A · Italy | 0–3 | Serie A · Italy |
| 2022-05-15 | NapolivGenoaSerie A · Italy | 3–0 | Serie A · Italy |
| 2022-05-07 | TorinovNapoliSerie A · Italy | 0–1 | Serie A · Italy |
| 2022-04-30 | NapolivSassuoloSerie A · Italy | 6–1 | Serie A · Italy |
| 2022-04-24 | EmpolivNapoliSerie A · Italy | 3–2 | Serie A · Italy |
| 2022-04-18 | NapolivRomaSerie A · Italy | 1–1 | Serie A · Italy |
| 2022-04-10 | NapolivFiorentinaSerie A · Italy | 2–3 | Serie A · Italy |
| 2022-04-03 | AtalantavNapoliSerie A · Italy | 1–3 | Serie A · Italy |
| 2022-03-19 | NapolivUdineseSerie A · Italy | 2–1 | Serie A · Italy |
| 2022-03-13 | VeronavNapoliSerie A · Italy | 1–2 | Serie A · Italy |
| 2022-03-06 | NapolivMilanSerie A · Italy | 0–1 | Serie A · Italy |
| 2022-02-27 | LaziovNapoliSerie A · Italy | 1–2 | Serie A · Italy |
| 2022-02-21 | CagliarivNapoliSerie A · Italy | 1–1 | Serie A · Italy |
| 2022-02-12 | NapolivInterSerie A · Italy | 1–1 | Serie A · Italy |
| 2022-02-06 | VeneziavNapoliSerie A · Italy | 0–2 | Serie A · Italy |
| 2022-01-23 | NapolivSalernitanaSerie A · Italy | 4–1 | Serie A · Italy |
| 2022-01-17 | BolognavNapoliSerie A · Italy | 0–2 | Serie A · Italy |
| 2022-01-09 | NapolivSampdoriaSerie A · Italy | 1–0 | Serie A · Italy |
| 2022-01-06 | JuventusvNapoliSerie A · Italy | 1–1 | Serie A · Italy |