| 2025-10-13 |  São Tomé and Príncipev MalawiFIFA World Cup qualification | 1–0 | FIFA World Cup qualification |
| 2025-10-10 |  TunisiavSão Tomé and PríncipeFIFA World Cup qualification | 6–0 | FIFA World Cup qualification |
| 2025-09-09 |  NamibiavSão Tomé and PríncipeFIFA World Cup qualification | 3–0 | FIFA World Cup qualification |
| 2025-09-04 | São Tomé and Príncipev Equatorial GuineaFIFA World Cup qualification | 2–3 | FIFA World Cup qualification |
| 2025-03-24 |  LiberiavSão Tomé and PríncipeFIFA World Cup qualification | 2–1 | FIFA World Cup qualification |
| 2025-03-21 | Equatorial GuineavSão Tomé and PríncipeFIFA World Cup qualification | 2–0 | FIFA World Cup qualification |
| 2024-06-09 | São Tomé and PríncipevLiberiaFIFA World Cup qualification | 0–1 | FIFA World Cup qualification |
| 2024-06-06 | MalawivSão Tomé and PríncipeFIFA World Cup qualification | 3–1 | FIFA World Cup qualification |
| 2023-11-21 | São Tomé and PríncipevNamibiaFIFA World Cup qualification | 0–2 | FIFA World Cup qualification |
| 2023-11-17 | TunisiavSão Tomé and PríncipeFIFA World Cup qualification | 4–0 | FIFA World Cup qualification |
| 2019-09-10 |  Guinea-BissauvSão Tomé and PríncipeFIFA World Cup qualification | 2–1 | FIFA World Cup qualification |
| 2019-09-04 | São Tomé and PríncipevGuinea-BissauFIFA World Cup qualification | 0–1 | FIFA World Cup qualification |
| 2015-10-11 |  EthiopiavSão Tomé and PríncipeFIFA World Cup qualification | 3–0 | FIFA World Cup qualification |
| 2015-10-08 | São Tomé and PríncipevEthiopiaFIFA World Cup qualification | 1–0 | FIFA World Cup qualification |
| 2011-11-15 |  CongovSão Tomé and PríncipeFIFA World Cup qualification | 1–1 | FIFA World Cup qualification |
| 2011-11-11 | São Tomé and PríncipevCongoFIFA World Cup qualification | 0–5 | FIFA World Cup qualification |
| 2003-11-16 |  LibyavSão Tomé and PríncipeFIFA World Cup qualification | 8–0 | FIFA World Cup qualification |
| 2003-10-11 | São Tomé and PríncipevLibyaFIFA World Cup qualification | 0–1 | FIFA World Cup qualification |
| 2000-04-22 |  Sierra LeonevSão Tomé and PríncipeFIFA World Cup qualification | 4–0 | FIFA World Cup qualification |
| 2000-04-08 | São Tomé and PríncipevSierra LeoneFIFA World Cup qualification | 2–0 | FIFA World Cup qualification |