| 2023-12-20 | Union BerlinvFC KolnBundesliga · Germany | 2–0 | Bundesliga · Germany |
| 2023-12-16 | BochumvUnion BerlinBundesliga · Germany | 3–0 | Bundesliga · Germany |
| 2023-12-09 | Union BerlinvM'gladbachBundesliga · Germany | 3–1 | Bundesliga · Germany |
| 2023-11-25 | Union BerlinvAugsburgBundesliga · Germany | 1–1 | Bundesliga · Germany |
| 2023-11-12 | LeverkusenvUnion BerlinBundesliga · Germany | 4–0 | Bundesliga · Germany |
| 2023-11-04 | Union BerlinvEin FrankfurtBundesliga · Germany | 0–3 | Bundesliga · Germany |
| 2023-10-28 | Werder BremenvUnion BerlinBundesliga · Germany | 2–0 | Bundesliga · Germany |
| 2023-10-21 | Union BerlinvStuttgartBundesliga · Germany | 0–3 | Bundesliga · Germany |
| 2023-10-07 | DortmundvUnion BerlinBundesliga · Germany | 4–2 | Bundesliga · Germany |
| 2023-09-30 | HeidenheimvUnion BerlinBundesliga · Germany | 1–0 | Bundesliga · Germany |
| 2023-09-23 | Union BerlinvHoffenheimBundesliga · Germany | 0–2 | Bundesliga · Germany |
| 2023-09-16 | WolfsburgvUnion BerlinBundesliga · Germany | 2–1 | Bundesliga · Germany |
| 2023-09-03 | Union BerlinvRB LeipzigBundesliga · Germany | 0–3 | Bundesliga · Germany |
| 2023-08-26 | DarmstadtvUnion BerlinBundesliga · Germany | 1–4 | Bundesliga · Germany |
| 2023-08-20 | Union BerlinvMainzBundesliga · Germany | 4–1 | Bundesliga · Germany |
| 2023-05-27 | Union BerlinvWerder BremenBundesliga · Germany | 1–0 | Bundesliga · Germany |
| 2023-05-20 | HoffenheimvUnion BerlinBundesliga · Germany | 4–2 | Bundesliga · Germany |
| 2023-05-13 | Union BerlinvFreiburgBundesliga · Germany | 4–2 | Bundesliga · Germany |
| 2023-05-06 | AugsburgvUnion BerlinBundesliga · Germany | 1–0 | Bundesliga · Germany |
| 2023-04-29 | Union BerlinvLeverkusenBundesliga · Germany | 0–0 | Bundesliga · Germany |
| 2023-04-23 | M'gladbachvUnion BerlinBundesliga · Germany | 0–1 | Bundesliga · Germany |
| 2023-04-16 | Union BerlinvBochumBundesliga · Germany | 1–1 | Bundesliga · Germany |
| 2023-04-08 | DortmundvUnion BerlinBundesliga · Germany | 2–1 | Bundesliga · Germany |
| 2023-04-01 | Union BerlinvStuttgartBundesliga · Germany | 3–0 | Bundesliga · Germany |
| 2023-03-19 | Union BerlinvEin FrankfurtBundesliga · Germany | 2–0 | Bundesliga · Germany |
| 2023-03-12 | WolfsburgvUnion BerlinBundesliga · Germany | 1–1 | Bundesliga · Germany |
| 2023-03-04 | Union BerlinvFC KolnBundesliga · Germany | 0–0 | Bundesliga · Germany |
| 2023-02-26 | Bayern MunichvUnion BerlinBundesliga · Germany | 3–0 | Bundesliga · Germany |
| 2023-02-19 | Union BerlinvSchalke 04Bundesliga · Germany | 0–0 | Bundesliga · Germany |
| 2023-02-11 | RB LeipzigvUnion BerlinBundesliga · Germany | 1–2 | Bundesliga · Germany |
| 2023-02-04 | Union BerlinvMainzBundesliga · Germany | 2–1 | Bundesliga · Germany |
| 2023-01-28 | HerthavUnion BerlinBundesliga · Germany | 0–2 | Bundesliga · Germany |
| 2023-01-25 | Werder BremenvUnion BerlinBundesliga · Germany | 1–2 | Bundesliga · Germany |
| 2023-01-21 | Union BerlinvHoffenheimBundesliga · Germany | 3–1 | Bundesliga · Germany |