| 2022-11-13 | FreiburgvUnion BerlinBundesliga · Germany | 4–1 | Bundesliga · Germany |
| 2022-11-09 | Union BerlinvAugsburgBundesliga · Germany | 2–2 | Bundesliga · Germany |
| 2022-11-06 | LeverkusenvUnion BerlinBundesliga · Germany | 5–0 | Bundesliga · Germany |
| 2022-10-30 | Union BerlinvM'gladbachBundesliga · Germany | 2–1 | Bundesliga · Germany |
| 2022-10-23 | BochumvUnion BerlinBundesliga · Germany | 2–1 | Bundesliga · Germany |
| 2022-10-16 | Union BerlinvDortmundBundesliga · Germany | 2–0 | Bundesliga · Germany |
| 2022-10-09 | StuttgartvUnion BerlinBundesliga · Germany | 0–1 | Bundesliga · Germany |
| 2022-10-01 | Ein FrankfurtvUnion BerlinBundesliga · Germany | 2–0 | Bundesliga · Germany |
| 2022-09-18 | Union BerlinvWolfsburgBundesliga · Germany | 2–0 | Bundesliga · Germany |
| 2022-09-11 | FC KolnvUnion BerlinBundesliga · Germany | 0–1 | Bundesliga · Germany |
| 2022-09-03 | Union BerlinvBayern MunichBundesliga · Germany | 1–1 | Bundesliga · Germany |
| 2022-08-27 | Schalke 04vUnion BerlinBundesliga · Germany | 1–6 | Bundesliga · Germany |
| 2022-08-20 | Union BerlinvRB LeipzigBundesliga · Germany | 2–1 | Bundesliga · Germany |
| 2022-08-14 | MainzvUnion BerlinBundesliga · Germany | 0–0 | Bundesliga · Germany |
| 2022-08-06 | Union BerlinvHerthaBundesliga · Germany | 3–1 | Bundesliga · Germany |
| 2022-05-14 | Union BerlinvBochumBundesliga · Germany | 3–2 | Bundesliga · Germany |
| 2022-05-07 | FreiburgvUnion BerlinBundesliga · Germany | 1–4 | Bundesliga · Germany |
| 2022-04-29 | Union BerlinvGreuther FurthBundesliga · Germany | 1–1 | Bundesliga · Germany |
| 2022-04-23 | RB LeipzigvUnion BerlinBundesliga · Germany | 1–2 | Bundesliga · Germany |
| 2022-04-17 | Union BerlinvEin FrankfurtBundesliga · Germany | 2–0 | Bundesliga · Germany |
| 2022-04-09 | HerthavUnion BerlinBundesliga · Germany | 1–4 | Bundesliga · Germany |
| 2022-04-01 | Union BerlinvFC KolnBundesliga · Germany | 1–0 | Bundesliga · Germany |
| 2022-03-19 | Bayern MunichvUnion BerlinBundesliga · Germany | 4–0 | Bundesliga · Germany |
| 2022-03-12 | Union BerlinvStuttgartBundesliga · Germany | 1–1 | Bundesliga · Germany |
| 2022-03-05 | WolfsburgvUnion BerlinBundesliga · Germany | 1–0 | Bundesliga · Germany |
| 2022-02-26 | Union BerlinvMainzBundesliga · Germany | 3–1 | Bundesliga · Germany |
| 2022-02-19 | BielefeldvUnion BerlinBundesliga · Germany | 1–0 | Bundesliga · Germany |
| 2022-02-13 | Union BerlinvDortmundBundesliga · Germany | 0–3 | Bundesliga · Germany |
| 2022-02-05 | AugsburgvUnion BerlinBundesliga · Germany | 2–0 | Bundesliga · Germany |
| 2022-01-22 | M'gladbachvUnion BerlinBundesliga · Germany | 1–2 | Bundesliga · Germany |
| 2022-01-15 | Union BerlinvHoffenheimBundesliga · Germany | 2–1 | Bundesliga · Germany |
| 2022-01-08 | LeverkusenvUnion BerlinBundesliga · Germany | 2–2 | Bundesliga · Germany |