| 2021-12-18 | BochumvUnion BerlinBundesliga · Germany | 0–1 | Bundesliga · Germany |
| 2021-12-15 | Union BerlinvFreiburgBundesliga · Germany | 0–0 | Bundesliga · Germany |
| 2021-12-12 | Greuther FurthvUnion BerlinBundesliga · Germany | 1–0 | Bundesliga · Germany |
| 2021-12-03 | Union BerlinvRB LeipzigBundesliga · Germany | 2–1 | Bundesliga · Germany |
| 2021-11-28 | Ein FrankfurtvUnion BerlinBundesliga · Germany | 2–1 | Bundesliga · Germany |
| 2021-11-20 | Union BerlinvHerthaBundesliga · Germany | 2–0 | Bundesliga · Germany |
| 2021-11-07 | FC KolnvUnion BerlinBundesliga · Germany | 2–2 | Bundesliga · Germany |
| 2021-10-30 | Union BerlinvBayern MunichBundesliga · Germany | 2–5 | Bundesliga · Germany |
| 2021-10-24 | StuttgartvUnion BerlinBundesliga · Germany | 1–1 | Bundesliga · Germany |
| 2021-10-16 | Union BerlinvWolfsburgBundesliga · Germany | 2–0 | Bundesliga · Germany |
| 2021-10-03 | MainzvUnion BerlinBundesliga · Germany | 1–2 | Bundesliga · Germany |
| 2021-09-25 | Union BerlinvBielefeldBundesliga · Germany | 1–0 | Bundesliga · Germany |
| 2021-09-19 | DortmundvUnion BerlinBundesliga · Germany | 4–2 | Bundesliga · Germany |
| 2021-09-11 | Union BerlinvAugsburgBundesliga · Germany | 0–0 | Bundesliga · Germany |
| 2021-08-29 | Union BerlinvM'gladbachBundesliga · Germany | 2–1 | Bundesliga · Germany |
| 2021-08-22 | HoffenheimvUnion BerlinBundesliga · Germany | 2–2 | Bundesliga · Germany |
| 2021-08-14 | Union BerlinvLeverkusenBundesliga · Germany | 1–1 | Bundesliga · Germany |
| 2021-05-22 | Union BerlinvRB LeipzigBundesliga · Germany | 2–1 | Bundesliga · Germany |
| 2021-05-15 | LeverkusenvUnion BerlinBundesliga · Germany | 1–1 | Bundesliga · Germany |
| 2021-05-08 | WolfsburgvUnion BerlinBundesliga · Germany | 3–0 | Bundesliga · Germany |
| 2021-04-24 | Union BerlinvWerder BremenBundesliga · Germany | 3–1 | Bundesliga · Germany |
| 2021-04-21 | DortmundvUnion BerlinBundesliga · Germany | 2–0 | Bundesliga · Germany |
| 2021-04-17 | Union BerlinvStuttgartBundesliga · Germany | 2–1 | Bundesliga · Germany |
| 2021-04-10 | Bayern MunichvUnion BerlinBundesliga · Germany | 1–1 | Bundesliga · Germany |
| 2021-04-04 | Union BerlinvHerthaBundesliga · Germany | 1–1 | Bundesliga · Germany |
| 2021-03-20 | Ein FrankfurtvUnion BerlinBundesliga · Germany | 5–2 | Bundesliga · Germany |
| 2021-03-13 | Union BerlinvFC KolnBundesliga · Germany | 2–1 | Bundesliga · Germany |
| 2021-03-07 | BielefeldvUnion BerlinBundesliga · Germany | 0–0 | Bundesliga · Germany |
| 2021-02-28 | Union BerlinvHoffenheimBundesliga · Germany | 1–1 | Bundesliga · Germany |
| 2021-02-20 | FreiburgvUnion BerlinBundesliga · Germany | 0–1 | Bundesliga · Germany |
| 2021-02-13 | Union BerlinvSchalke 04Bundesliga · Germany | 0–0 | Bundesliga · Germany |
| 2021-02-06 | MainzvUnion BerlinBundesliga · Germany | 1–0 | Bundesliga · Germany |
| 2021-01-30 | Union BerlinvM'gladbachBundesliga · Germany | 1–1 | Bundesliga · Germany |
| 2021-01-23 | AugsburgvUnion BerlinBundesliga · Germany | 2–1 | Bundesliga · Germany |
| 2021-01-20 | RB LeipzigvUnion BerlinBundesliga · Germany | 1–0 | Bundesliga · Germany |
| 2021-01-15 | Union BerlinvLeverkusenBundesliga · Germany | 1–0 | Bundesliga · Germany |
| 2021-01-09 | Union BerlinvWolfsburgBundesliga · Germany | 2–2 | Bundesliga · Germany |
| 2021-01-02 | Werder BremenvUnion BerlinBundesliga · Germany | 0–2 | Bundesliga · Germany |