| 2020-10-18 | Schalke 04vUnion BerlinBundesliga · Germany | 1–1 | Bundesliga · Germany |
| 2020-10-02 | Union BerlinvMainzBundesliga · Germany | 4–0 | Bundesliga · Germany |
| 2020-09-26 | M'gladbachvUnion BerlinBundesliga · Germany | 1–1 | Bundesliga · Germany |
| 2020-09-19 | Union BerlinvAugsburgBundesliga · Germany | 1–3 | Bundesliga · Germany |
| 2020-06-27 | Union BerlinvFortuna DusseldorfBundesliga · Germany | 3–0 | Bundesliga · Germany |
| 2020-06-20 | HoffenheimvUnion BerlinBundesliga · Germany | 4–0 | Bundesliga · Germany |
| 2020-06-16 | Union BerlinvPaderbornBundesliga · Germany | 1–0 | Bundesliga · Germany |
| 2020-06-13 | FC KolnvUnion BerlinBundesliga · Germany | 1–2 | Bundesliga · Germany |
| 2020-06-07 | Union BerlinvSchalke 04Bundesliga · Germany | 1–1 | Bundesliga · Germany |
| 2020-05-31 | M'gladbachvUnion BerlinBundesliga · Germany | 4–1 | Bundesliga · Germany |
| 2020-05-27 | Union BerlinvMainzBundesliga · Germany | 1–1 | Bundesliga · Germany |
| 2020-05-22 | HerthavUnion BerlinBundesliga · Germany | 4–0 | Bundesliga · Germany |
| 2020-05-17 | Union BerlinvBayern MunichBundesliga · Germany | 0–2 | Bundesliga · Germany |
| 2020-03-07 | FreiburgvUnion BerlinBundesliga · Germany | 3–1 | Bundesliga · Germany |
| 2020-03-01 | Union BerlinvWolfsburgBundesliga · Germany | 2–2 | Bundesliga · Germany |
| 2020-02-24 | Ein FrankfurtvUnion BerlinBundesliga · Germany | 1–2 | Bundesliga · Germany |
| 2020-02-15 | Union BerlinvLeverkusenBundesliga · Germany | 2–3 | Bundesliga · Germany |
| 2020-02-08 | Werder BremenvUnion BerlinBundesliga · Germany | 0–2 | Bundesliga · Germany |
| 2020-02-01 | DortmundvUnion BerlinBundesliga · Germany | 5–0 | Bundesliga · Germany |
| 2020-01-25 | Union BerlinvAugsburgBundesliga · Germany | 2–0 | Bundesliga · Germany |
| 2020-01-18 | RB LeipzigvUnion BerlinBundesliga · Germany | 3–1 | Bundesliga · Germany |
| 2019-12-22 | Fortuna DusseldorfvUnion BerlinBundesliga · Germany | 2–1 | Bundesliga · Germany |
| 2019-12-17 | Union BerlinvHoffenheimBundesliga · Germany | 0–2 | Bundesliga · Germany |
| 2019-12-14 | PaderbornvUnion BerlinBundesliga · Germany | 1–1 | Bundesliga · Germany |
| 2019-12-08 | Union BerlinvFC KolnBundesliga · Germany | 2–0 | Bundesliga · Germany |
| 2019-11-29 | Schalke 04vUnion BerlinBundesliga · Germany | 2–1 | Bundesliga · Germany |
| 2019-11-23 | Union BerlinvM'gladbachBundesliga · Germany | 2–0 | Bundesliga · Germany |
| 2019-11-09 | MainzvUnion BerlinBundesliga · Germany | 2–3 | Bundesliga · Germany |
| 2019-11-02 | Union BerlinvHerthaBundesliga · Germany | 1–0 | Bundesliga · Germany |
| 2019-10-26 | Bayern MunichvUnion BerlinBundesliga · Germany | 2–1 | Bundesliga · Germany |
| 2019-10-19 | Union BerlinvFreiburgBundesliga · Germany | 2–0 | Bundesliga · Germany |
| 2019-10-06 | WolfsburgvUnion BerlinBundesliga · Germany | 1–0 | Bundesliga · Germany |
| 2019-09-27 | Union BerlinvEin FrankfurtBundesliga · Germany | 1–2 | Bundesliga · Germany |
| 2019-09-21 | LeverkusenvUnion BerlinBundesliga · Germany | 2–0 | Bundesliga · Germany |
| 2019-09-14 | Union BerlinvWerder BremenBundesliga · Germany | 1–2 | Bundesliga · Germany |
| 2019-08-31 | Union BerlinvDortmundBundesliga · Germany | 3–1 | Bundesliga · Germany |
| 2019-08-24 | AugsburgvUnion BerlinBundesliga · Germany | 1–1 | Bundesliga · Germany |
| 2019-08-18 | Union BerlinvRB LeipzigBundesliga · Germany | 0–4 | Bundesliga · Germany |