| 1989-07-08 |  Boliviav ChileCopa América | 0–5 | Copa América |
| 1989-07-06 |  EcuadorvBoliviaCopa América | 0–0 | Copa América |
| 1989-07-04 |  UruguayvBoliviaCopa América | 3–0 | Copa América |
| 1987-07-01 | Boliviav ColombiaCopa América | 0–2 | Copa América |
| 1987-06-28 |  ParaguayvBoliviaCopa América | 0–0 | Copa América |
| 1983-09-04 |  PeruvBoliviaCopa América | 2–1 | Copa América |
| 1983-08-31 | ColombiavBoliviaCopa América | 2–2 | Copa América |
| 1983-08-21 | BoliviavPeruCopa América | 1–1 | Copa América |
| 1983-08-14 | BoliviavColombiaCopa América | 0–1 | Copa América |
| 1979-08-16 |  BrazilvBoliviaCopa América | 2–0 | Copa América |
| 1979-08-08 |  ArgentinavBoliviaCopa América | 3–0 | Copa América |
| 1979-07-26 | BoliviavBrazilCopa América | 2–1 | Copa América |
| 1979-07-18 | BoliviavArgentinaCopa América | 2–1 | Copa América |
| 1975-08-13 | ChilevBoliviaCopa América | 4–0 | Copa América |
| 1975-08-07 | PeruvBoliviaCopa América | 3–1 | Copa América |
| 1975-07-27 | BoliviavPeruCopa América | 0–1 | Copa América |
| 1975-07-20 | BoliviavChileCopa América | 2–1 | Copa América |
| 1967-02-01 | BoliviavChileCopa América | 0–0 | Copa América |
| 1967-01-28 | Boliviav VenezuelaCopa América | 0–3 | Copa América |
| 1967-01-25 | ParaguayvBoliviaCopa América | 1–0 | Copa América |
| 1967-01-22 | BoliviavArgentinaCopa América | 0–1 | Copa América |
| 1967-01-17 | UruguayvBoliviaCopa América | 4–0 | Copa América |
| 1963-03-31 | BoliviavBrazilCopa América | 5–4 | Copa América |
| 1963-03-28 | BoliviavArgentinaCopa América | 3–2 | Copa América |
| 1963-03-24 | BoliviavParaguayCopa América | 2–0 | Copa América |
| 1963-03-21 | BoliviavPeruCopa América | 3–2 | Copa América |
| 1963-03-17 | BoliviavColombiaCopa América | 2–1 | Copa América |
| 1963-03-10 | BoliviavEcuadorCopa América | 4–4 | Copa América |
| 1959-03-29 | BoliviavPeruCopa América | 0–0 | Copa América |
| 1959-03-26 | BoliviavChileCopa América | 2–5 | Copa América |
| 1959-03-21 | BoliviavBrazilCopa América | 2–4 | Copa América |
| 1959-03-15 | BoliviavParaguayCopa América | 0–5 | Copa América |
| 1959-03-11 | ArgentinavBoliviaCopa América | 2–0 | Copa América |
| 1959-03-08 | BoliviavUruguayCopa América | 0–7 | Copa América |
| 1953-03-28 | BoliviavChileCopa América | 2–2 | Copa América |
| 1953-03-16 | BoliviavParaguayCopa América | 1–2 | Copa América |
| 1953-03-08 | BoliviavEcuadorCopa América | 1–1 | Copa América |
| 1953-03-01 | BoliviavBrazilCopa América | 1–8 | Copa América |
| 1953-02-25 | BoliviavUruguayCopa América | 0–2 | Copa América |
| 1953-02-22 | PeruvBoliviaCopa América | 0–1 | Copa América |
| 1949-05-06 | BoliviavColombiaCopa América | 4–0 | Copa América |
| 1949-04-30 | BoliviavParaguayCopa América | 0–7 | Copa América |
| 1949-04-27 | BoliviavPeruCopa América | 0–3 | Copa América |
| 1949-04-25 | BoliviavEcuadorCopa América | 2–0 | Copa América |
| 1949-04-17 | BoliviavUruguayCopa América | 3–2 | Copa América |
| 1949-04-10 | BrazilvBoliviaCopa América | 10–1 | Copa América |
| 1949-04-06 | BoliviavChileCopa América | 3–2 | Copa América |
| 1947-12-31 | BoliviavChileCopa América | 3–4 | Copa América |
| 1947-12-27 | BoliviavPeruCopa América | 0–2 | Copa América |
| 1947-12-18 | BoliviavParaguayCopa América | 1–3 | Copa América |